Methanol steam reforming for hydrogen generation via conventional and membrane reactors. Considering the overall device as an array of unit cells enabled simplified modeling of the. Optimal design of an experimental methanol fuel reformer. Transient behaviour of a small methanol reformer for fuel. The oxygen is admitted to the secondary reformer through the cts burner in the reformer neck.
Environmental and human health considerations for methanol as. Compact reformer bundle, incorporating several design improvements, was installed and successfully commissioned. Pdf study of different designs of methanol steam reformers. Examine the systems implications of new reformer technologies for distributed and. Pdf three reformers with different designs multichannel, radial and tubular were. Synthesis gas processes for methanol production via ch4. Some design considerations, author kumar, r and ahmed, s and krumpelt, m and myles, k m, abstractnote fuel cells are being developed for use in automotive propulsion systems as alternatives for the internal combustion engine in buses, vans, passenger cars. The capacity of methanol plant has increased by 300 mtpd with addition of co2 in synthesis gas mixture as excess h2 is available for the methanol reaction. Phase ii university of california, davis date of report. Methanol is produced from syngas via the fischertropsch process, given by eqn. Methanol ch3oh is a liquid chemical used in thousands of everyday. The design of the fuel cell vehicle is simpler with onboard hydrogen. Accepted for publication in chemical engineering and technology.
Reformer furnace outlet systems 6 methane slip in the 5. The decomposition of methanol leads to a product gas containing up to 67% hydrogen and 33% carbon monoxide. Three design cases with different reforming technologies in. John bogild hansen haldor topsoe methanol workshop, lund university march 17, 2015. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu. Design and manufacture of reformer in polymer electrolyte. The reformer uses synetix 335 steam methanol reforming catalyst. Dizajn i proizvodnja reformera za gorivne celije sa polimerskom. Methanol steam reformer high temperature pem fuel cell system. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad. Process design overview for upgrading a gastomethanol facility.
Steam reformer furnace design will continue to develop along with methods to implement combustion safety in these furnaces. Novel reformer technologies such as sorbent enhanced. Steam reforming of methanol for fuel cell grade hydrogen. Methanol reformer design considerations wiley online library. The effectiveness of all types of processors substantially depends on the temperature control of methanol steam reformer. Presentation outline introduction background of methanol feed selection location and market process alternatives equipment costing safety economic analysis conclusions and future considerations questions 225 3. The models included all the feed pretreatment steps along with the reforming reactors and effluent treatment. The methanol institute mi serves as the global trade association for one of the worlds most vibrant and innovative industries. Steam reforming of methanol for fuel cell applications. The methods of reforming include partial oxidation, autothermal, steam reforming and so. Experiment and modeling article pdf available in international journal of hydrogen energy 3935 october 2014 with 402 reads. Pdf miniaturized methanol reformer for fuel cell powered.
Review of small stationary reformers for hydrogen production. Figure 1 davy compact reforming installed on the nikiski demonstration plant. Three different methanol reformer designs for thermal integration with an htpemfc were thoroughly studied experimentally and by cfd simulation. A h2 separation process is considered for syngas composition adjustment. A compact gastomethanol process and its application to. Methanol steam reforming in a dual bed membrane reactor for. With a reformer, the main design considerations are its physical dimensions, its response rate after cold start and its transient response during acceleration. The results showed that the multichannel design is the best solution for the thermal integration, with high methanol conversion and low pressure drop.
The reforming of methanol requires temperatures of 2000c or higher, while the reforming of ethanol or hydrocarbons requires temperatures 4500c. Molecular catalysts for hydrogen production from alcohols. A wide variety of steam reformer designs, configurations, and component equipment exists today. Fuel reformation and hydrogen generation with direct. Dingler satish nirula walter sedriks february 1983 a private report by the. Methanol does not bind well to soil and will evaporate from soil when exposed to air. Monolithic substrate support catalyst design considerations for steam methane reforming operation. Indeed, because of the overriding heat transfer considerations, steam reformers are typictjly designed as heat exchangers and often incorporate special design. Design and development of an autothermal reformer for fuel cell applications. In low concentrations, methanol can quickly biodegrade in moist soils and groundwaters. Sep 24, 20 steam reforming types of reformer design 1. Inspection methods design principles recent developments in metallurgy failure mechanisms monitoring and inspection techniques.
The billingham site originally produced syngas from steaming coke, but this process is only 40% ef. Methanol steam reforming for fuel cell applications. Design of process plant for producing hydrogen from steam. Other major design considerations are of course the maximization of hydrogen production for the fuel cell and minimization of carbon monoxide in the reactor. Autothermal reforming of natural gas to synthesis gas. Study of different designs of methanol steam reformers.
A steam reformer better lends itself to thermal integration with the fuel cell system. The initial geometry of the reaction volume with channels is shown in fig. These results were compared with results for all gasoline. A study of ethanol and methanol as a fuel for onboard hydrogen generation by steam reforming on copperbased. The most simple conversion method, as only methanol is used in the feeding, is thermal or catalytic decomposition eq. Design and implementation of an opticalaccess steam methanol. Stainless steel jacketedtube reactor was separately used for methanol oxidation oxd and methanol steam reforming reactions srr, respectively, a tubular coil 3. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c. Development of a methanol reformer for fuel cell vehicles. Perhaps harder to quantify is the indirect health risk of greenhouse gas emissions resulting from methanol fuel production. Monolithic substrate support catalyst design considerations. The experimental effort was then focused on a series of measurements to evaluate rich, highpressure burner behavior at pressures as high as 500 psi.
Design and evaluation of heat utilization systems for. Equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup, and oxygen separation equipment. Methanol is transformed into hydrogen and carbon dioxide by pressure and heat and interaction with a catalyst. Reformer furnace outlet systems 3 background the issue steam. Reformer watpump steamgen hts lts cond1 gascomp hierarchy amine methantr treated treated2 hotprod q q energy inputs energy removal kcalhr kw kcalhr steam boiler 3,742,371 post reformer cooler 2,238,933 reformer 6,332,965 post hts cooler 1,026,525 amine duty 5,680,514 post lts cooler 2,305,814 methanator reheat 553,190 amine coolers 3,550,321. There are no significant byproducts or intermediates. Apparent flame speed wasused to describe the differ ences in emissions and performance. Three major types of reformer each tackles the duty in different ways no clear best choice choice dictated by contractor history 3. Developmentcommercialization status of methanol steam reformers. Catalytic oxidation of liquid methanol as a heat source for an automotive reformer.
The various hydrogen production schemes were investigated for three different fuels. It also depends on the efficiency of heat transfer between the reformer and an external heat source, for example, the catalytic combustor. Using these basic considerations as guidelines, different reactor designs are discussed and examples given. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture. Equipment design and cost estimation for small modular.
Tubular reformer for methanol plant based on two step reforming. Methanol is a liquid fuel that is light, colorless, stable, and biodegradable methanol contains more hydrogen than any other liquid fuel methanol can be sourced regionally, and is produced globally at over 90 plants producing almost 24 billion gallons annually methanol is easily mixed with purified water in a batch process by local. These may support the production of ammonia, methanol, gas. Pdf basic design of tubular steam reformer chathura. From 1928, research work on methane reforming started at billingham. The various processes and operating conditions of electrolysis, steam reforming and methanol cracking have diverse investment costs, fig. We have been committed to catalytic process technology for more than 70 years. Ideal for small to medium size plant capacities andor feedstocks with high co 2 content, topsoes onestep methanol plant relies exclusively on our efficient, reliable and easytooperate sidefired reforming design for generating hydrogenrich syngas. A tubular structure reactor was fabricated as shown in fig 1. Markets served modular hydrogen plants with typical capacities from 150 to 12,000 nm3h are designed with the. An overview is presented here of the major process design considerations evaluated and implemented for the upgrade of an existing naturalgasto methanol plant. When it is released into soil, methanol can move through it and enter groundwater. In both systems the methanol reformer operates at 250 c and steamtomethanol ratio of 1. The plant is located in beaumont, texas and was built in 1967 by dupont with an original capacity of 550 metric mtpy of methanol from natural gas.
Process design overview for upgrading a gastomethanol. The compact reformer is small and lightweight and can be readily transported by road or rail, making it ideal for use in remote or offshore locations. Further background information is available in refs. Both steam reforming and partial oxidation with steam, air and methanol are considered. June 07, 2006 design group one elton amirkhas raj bedi steve harley trevor lango report executive summary this report is the first phase of a final report designed to investigate the feasibility of methanol production in trinidad and tobago. The overall objective of this project is to design and optimize a grassroots facility capable of producing 500 million standard cubic feet scf per day of synthesis gas based on carbon monoxide co for further. Org 500 mtpd of co2 is recovered from the flue gas using mhis proprietary ks1 solvent and injected in synthesis loop for boosting methanol production.
Design configurations of the methanol synthesis loop. In fixed bed reactors, depending on the specific design of the reactor, the. The equilibrium composition out of the steam reformer is shown in fig. Fundamental factors in the design of a fastresponding. Steam reforming of methane for the production of hydrogen and methanol. Design of compact methanol reformer for hydrogen with low. These include steam methane reforming smr, partial oxidation pox, autothermal reforming atr, methanol reforming, ammonia cracking and catalytic cracking of methane. In the heatric process natural gas, including quite high concentrations of co2, is steam reformed and then converted to methanol in a unique oncethrough reactor design, with hydrogenrich tail gas being combusted to heat the reformer. Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. What is methanol, its uses, energiesmethanol institute. See a diagram of topsoes steam reformer based methanol process. Dec 15, 2010 both steam reforming and partial oxidation with steam, air and methanol are considered. The reactor designs based on steam reforming alone mainly differ with respect to the method by which the heat is provided for the endothermal overall.
With growing worldwide natural gas reserves and recent advances in methanol technology, methanol may be poised to take on renewed importance in the fuels and petrochemical markets. Methanol and other alternative fuels must be converted reformed to a hydrogenrich gas for such fuels to be used in fuel cells. In this contribution, we report on the steadystate modeling and design optimization of a 1. There are a number of considerations in the design of fuel reforming systems 1. Comparison of efficiency between systems with a high temperature ht pemfc stack and a classical, lowtemperature lt pemfc stack has been made. With over 50 years experience in plant design, engineering, procurement and construction, our production facilities are among the safest and most reliable on the planet and produce the highest quality product.
In this paper, the design of a miniaturized methanol reformer is considered that can operate in two different modes to produce sufficient hydrogen for generating a net power of 24 w and 72 w. For a comparative study, the hypothetical expansion of an existing methanol plant based on steam reforming of natural gas was chosen. Minimizing carbon monoxide production is an important consideration for fuel. The partially reformed gas from the tubular reformer is transferred to the secondary reformer, where the reforming is completed by catalytic partial oxidation. Nonsyngas direct steam reforming of methanol to hydrogen and. The methanolloop reactor was also included in the analysis to take into account its close relationship with the reformers energy balance. Autothermal reforming of natural gas to synthesis gas reference. Reformers for the production of hydrogen from methanol and. On most methanol plants we only have a primary reformer therefore must minimize methane slip from primary methane is an inert in the loop just like ammonia represents an inefficiency must be purged out lose reactants purge is burned in reformer typically 23 of the reformer fuel some plant do sell it. Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of natural gas.
The design of the steam reforming process is in part dictated by these constraints. Ohi department of mechanical engineering and applied mechanics, university of michigan, 2292 gg brown, ann arbor, mi 481092125. Only 210 reformer tubes are used for the production of 2,400 mtpd methanol. Hydrogen can be extracted by the reforming process from methanol, natural gas, fossil fuel etc. In this project, you will utilize your process design knowledge to develop candidate process flowsheets from the initial concept through material balances, equipment sizing, control system design, and economic analysis. The consideration of alternative reforming technologies resulted from the everrising. Cfd modeling of compact methanol reformer sciencedirect. Methanol reformer design considerations hansen major. Hawkins managing director, ceo c2pt catalyst process technology 2. Founded in 1989, mi now serves its members in every corner of the globe from our offices in singapore, washington, d. Advanced modelling and optimisation of natural gas.